Batch experiments were conducted to study the effect of reaction parameters on the adsorption of the dye such as. Batch experiments were conducted to study the effects of ph, initial concentration of adsorbate and temperature on dye adsorption. Methyl orange mo and ethyl orange eo were selected as models of dye molecules. The adsorption behavior of methyl orange dye from aqueous solution onto activated lignin was investigated as a function of equilibrium time, ph and concentration. Enhanced adsorption of methyl orange by vermiculite. Pdf chitosan was utilized as adsorbent to remove methyl orange mo from aqueous solution by adsorption. The effect of ph 310, adsorbent dose gl, initial mo dye concentration 10100 mgl. Preparation and characterization of activated carbon from. The kinetics and adsorption mechanism of methyl orange mo onto chitosan 10b were studied in the present work. Nov 15, 2019 results showed that on increasing adsorbent dosage from 0. Adsorption of methyl orange dye using femn composite powder. The purpose was to provide a new adsorption material for the treatment of methyl orange wastewater, and to provide a scientific basis. The adsorption behavior of methyl orange aqueous solution was investigated on huskbased activated carbon.
Comparative study of the adsorption of methyl orange by bentonite. Determination of biosorption conditions of methyl orange by. Adsorption of methylene blue on cellulose from its own. The adsorption of methyl orange mo from aqueous solutions onto a kohactivated polypyrrolebased adsorbent pack was investigated using batch and. Thermodynamics and adsorption study of methyl orange onto. The parameters affecting the adsorption of methyl orange mo dye by ahm such as ph, adsorbent dosage, contact time, initial. Pdf this paper present the efficiency of animal activated carbon in removal of methyl orange mo from aqueous solutions by adsorption. An adsorption kinetic study revealed a preferably pseudosecondorder r2 0.
Removal of methyl orange from aqueous solution via adsorption. Modeling of experimental data for the adsorption of methyl orange from aqueous solution using a low cost activated carbon prepared from prosopis juliflora. Simultaneous adsorption of methyl orange and heavy metals. Adsorption of methyl orange dye using femn composite powder as adsorbent. Original research adsorption properties of methyl orange in. Adsorption of methylorange from aqueous solution onto. Sep 11, 2018 activated carbon acpolytetrafluoroethylene ptfe electrodes were prepared and applied for methyl orange mo adsorption and electrofenton regeneration. The adsorption of methyl orange dye on activated carbon and bentonite type algerian clay from aqueous solutions was investigated. Integration of adsorption and photocatalytic degradation of methyl orange using tio 2 ass nanocomposite the experiments were carried out in two consecutive conditions. Activated carbon derived from finger citron residue fac was tested as a new type of adsorbent for the removal of harmful dyes, namely, the anionic dye methyl orange mo and the cationic dye methylene blue mb, from contaminated water. Pdf adsorption of methyl orange onto chitosan from aqueous. Equilibrium and kinetic adsorption studies of methyl orange. Methyl orange mo was purchased from fluka chemika supplier company.
Introduction time is crucial to the success of most chemical processes. Adsorption of methyl orange from aqueous solution on anion exchange membranes. Batch experiments showed that both the initial dye concentration and the ph of aqueous solutions significantly affect the adsorption capacity of dye mo on the chitosan 10b. The adsorption of methyl orange mo from aqueous solutions on protonated crosslinked chitosan was studied in a batch system.
The parameters affecting the adsorption process such as. Adsorption of azo dye methyl orange from aqueous solutions. Adsorption of methyl orange onto chitosan from aqueous. The adsorption of methyl orange mo from aqueous solutions onto a kohactivated polypyrrolebased adsorbent pack was. However, due to the ionic nature of methyl orange, the retention of the dye by ionexchange processes3,src, particularly on clay surfaces, and adsorption at mineral surfaces such as geothite4,src, may lead to increased adsorption on some sediment and particulate surfacessrc.
Effect of time on the adsorption of methylene blue, methyl. Jun 29, 2012 the results showed that the surface area and micropores volume of activated carbon at the experimental conditions are achieved to 587 and 0. The adsorptive removal of methyl orange dye using a sugar beet bagasse sbb as agroindustrial byproduct has been investigated. This material is unprecedented, and the modification method used to obtain it is relatively simple. The data fit onto this model is good suggesting that the adsorption process onto the adsorbent is overall third order which implies that the rate determining step in the mechanism involves three bodies colliding at the same time for instance two methyl orange molecules and an adsorption site or one methyl orange molecule, a solvent molecule. Our original solvothermal method to obtain magnetic iron oxidecarbon nanocomposites, uses 1,2propanediol as solvent, koh as precipitant and activated carbon, with a specific surface area of 890 m 2 g. The kinetic data obtained from different batch experiments were analyzed using. Abstractin this study, the cork powder was used as adsorbent to remove methyl orange mo from aqueous solutions by adsorption. Adsorption properties of methyl orange in water by sheep manure.
Single and binary adsorption of sulfonamide antibiotics onto ironmodified clay. Batch adsorption experiments were carried out utilizing the composite films to adsorb a typical azo dye, i. Abstract in this work, the removal of methyl orange. Kinetic study of methyl orange adsorption on activated carbon derived from pine pinus strobus sawdust, biores. Batch adsorption experiments were carried out as a function of ph, contact time, adsorbate concentration, adsorbent dosage and. Pdf equilibrium and kinetic adsorption studies of methyl.
Investigation of methyl orange adsorption from water using. Competitive adsorption of methyl orange and ethyl orange by. Keywords adsorption, methyl orange, lobatse clay, kinetics, thermodynamics. Modeling of experimental data for the adsorption of methyl.
Mar 11, 2020 the adsorption behavior and mechanism of aminocrosslinked hypromellose ahm adsorbent crosslinked with epichlorohydrin and modified with diethylenetriamine were studied. Various conditions were evaluated, including initial. Preparation and characterization of activated carbon from date pits by chemical activation with zinc chloride for methyl orange adsorption khaled mahmoudi, noureddine hamdi, ezzeddine srasra laboratory of physicochemical of minerals materials and its applications national centre of research in materials sciences cnrsm b. The structural, thermal, and morphological properties of the pack, analyzed by various methods. Liquidphase adsorption experiments were conducted, and the maximum adsorption capacity was determined. Benefit of hydrophilicity for adsorption of methyl orange and. Adsorption of methyl orange onto protonated crosslinked. Adsorption kinetics and equilibrium muhammad imran khan, liang wu, abhishek n. Synthesis, characterisation and methyl orange adsorption. The optimum dosage for both the systems was found to be 0. This study utilized swietenia mahagoni barka wood processing industry waste, for the preparation of activated carbon, and then investigated for the removal of methyl orange mo dye by the swietenia mahagoni bark activated carbon smbac. Adsorption behavior and kinetics of methyl orange in water on.
G, showed that the adsorption is endothermic, random and nonspontaneous at high temperature. The adsorption of methyl orange mo from aqueous solutions onto a kohactivated polypyrrolebased adsorbent pack was investigated using batch and fixedbed column techniques. Removal of methyl orange mo from water by adsorption onto. In a wastewater resulted from the dyes finishing industry there are amounts of dyes very common methyl orange and heavy metals resulted mainly from the organometallic dyes. The results indicate that fb adsorbs mo efficiently and could be utilized as a lowcost alternative adsorbent for the removal of anionic dyes in wastewater treatment. Batch adsorption experiments were carried out as a function of ph, contact time, adsorbate concentration, adsorbent dosage and temperature. Kurupstudies on the adsorption kinetics and isotherms for the removal and recovery of methyl orange from wastewaters using waste materials j. Characterization of aminocrosslinked hypromellose and its. This paper presents the feasibility for the removal of methyl orange mo dye from aqueous solution using an activated carbon prepared from prosopis juliflora bark. The parameters affecting the adsorption of methyl orange mo dye by ahm such as ph, adsorbent. Batch experiments were conducted to study the effects of ph, initial concentration of adsorbate. Eo has only two methylenes more than mo, which makes it facile to analyze the effect of ph and ionic strength on the competitive adsorption of these dyes. Results showed that on increasing adsorbent dosage from 0.
The equilibrium data on the methyl orange fitted to both langmuir and. Adsorption, methylene blue, methyl orange, indigocarmine. Kinetic study of methyl orange adsorption on activated carbon. Department of civil engineering national institute of technology agartala agartala, india. Single and simultaneous adsorption of methyl orange and phenol onto magnetic iron oxidecarbon nanocomposites roxana istratiea, marcela stoiaa,b, cornelia pa. No matter how many components are present in the system, the adsorption equilibria of pure components are the essential ingredient for the understanding of how much those components can be accommodated by a solid adsorbent duong, 1998. Adsorption and photocatalysis for methyl orange and cd. The adsorption potential of sbb was improved by grafting with fecl3. Adsorption of methyl orange onto chitosan from aqueous solution. Removal of methyl orange from aqueous solutions by magnetic.
The purpose was to provide a new adsorption material for the treatment of methyl orange wastewater, and to provide a scientific basis for the new resource utilization method of sheep manure. Adsorption of methyl orange dye using femn composite. In this study, efficiency of kaolinite kao, metakaolinite mk and activated geopolymer geo7 as adsorbents for the removal of methyl orange mo in aqueous solution were investigated. The structural, thermal, and morphological properties of the pack, analyzed by various methods, support its applicability as an adsorbent. Activated carbon acpolytetrafluoroethylene ptfe electrodes were prepared and applied for methyl orange mo adsorption and electrofenton regeneration. Adsorption of methyl orange onto chitosan from aqueous solution article pdf available in journal of water resource and protection 210. The effects of adsorbent dosage, solution ph, coexisting anions, and temperature were studied.
The chemical structure and properties of methyl orange are recorded in table 1. Application of response surface methodology for optimization. Mo dye by adsorption on silver nanoparticles agnps coated activated carbon ac has. Mondal, zilu yao, liang ge and tongwen xu cas key laboratory of soft matter chemistry, lab of functional membranes, school of chemistry and material science, university of science and. Removal of methyl orange by activated carbon modified by.
Adsorption of methyl orange dye using femn composite powder as adsorbent akash deb department of civil engineering national institute of technology agartala agartala, india abstract in this study femn composite powder was synthesized and used as an adsorbent for the removal of methyl orange mo from aqueous solution. Aqueous solutions were prepared using distilled water. Figure 4 shows the effects of temperature on the adsorption of methyl orange. The adsorption of methyl orange onto vermiculite and ctmabvermiculite was studied at different ph levels, varying from 3 to 11 fig. Adsorption of methyl orange onto protonated crosslinked chitosan.
Adsorption behavior of methyl orange onto an aluminumbased. Chitosan was utilized as adsorbent to remove methyl orange mo from aqueous solution by adsorption. The powders obtained at 195 c were all magnetic, with no phase separation under the action of a magnet, suggesting the formation of a. Adsorption of methyl orange using activated carbon prepared. Biosorption conditions of methyl orange by humicola fuscoatra 1077 higher ph led to lower adsorption because of characteristics of biomass and methyl orange, which can also be seen in many other dyes and most of the researchers claimed that an acidic ph condition of dye solution was more effective for dye removal10,14,15. The addition of ptfe to ac significantly decreased the hydrophilicity, which in turn, decreased both the amount of mo adsorbed and the regeneration efficiency. Removal of methyl orange dye from aqueous solution by a low. Adsorption of methyl orange from aqueous solution by aminated. Adsorptive removal of methyl orange and methylene blue from. The adsorption behavior and mechanism of aminocrosslinked hypromellose ahm adsorbent crosslinked with epichlorohydrin and modified with diethylenetriamine were studied. The results showed that the surface area and micropores volume of activated carbon at the experimental conditions are achieved to 587 and 0. Generally, the ph of the adsorption depends on the zero point charge of the methyl orange phzpc and the charge of the adsorbent surface.
Adsorption isotherms, methyl orange, kinetic models, activated carbon an adsorption process. Notably, it is a referred, highly indexed, online international journal with high impact factor. Single and simultaneous adsorption of methyl orange and. Pdf modeling of experimental data for the adsorption of. Abstract in this study femn composite powder was synthesized and used as an adsorbent for the removal of methyl orange mo from aqueous solution. Kinetics studies on the adsorption of methyl orange and.
Kinetic studies and equilibrium isotherm analyses for the. Kinetic studies and equilibrium isotherm analyses for the adsorption of methyl orange by coal fly ash from aqueous solution. Thermodynamics and adsorption study of methyl orange. The effects of temperature and kcl on the adsorption. The effects of ph, biochar dosage, adsorption time, temperature on adsorption of methyl orange mo in water by sheep manure biochar. The adsorption behaviour of the cationic dye, methylene blue mb from its own solution and from its mixture with an anionic dye, methyl orange mo on cellulose has been investigated. Notably, it is a referred, highly indexed, online international journal with. In this case the uptake of mo increased with decrease in temperature indicating that adsorption of methyl orange onto the clay is favoured by lower temperatures and also that the adsorption process was exothermic 24. The adsorption behavior of an azo dye methyl orange mo on aluminum oxide nano particles anp generated by sol gel method has been performed to understand the physicochemical process involved and to explore the potential use of nano particles in textile effluent treatment and management. Freundlich model best indicating heterogeneity of the surface of the clay sample.
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